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Frontiers of Multifunctional Nanosystems

May 28, 2010 by · Leave a Comment 

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Discusses the realization and characterization of the fundamental properties of nanosystems, defined by nano-size effects, as well as the application of such systems in electronics, optics, magnetoelectronics, spintronics, biomedicine, pharmaceutical biocomplexes, and biosensors.

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Nanoporous Materials: Science and Engineering

May 24, 2010 by · Leave a Comment 

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Porous materials are of scientific and technological importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the “nothingness” within — the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories — micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, nanoporous materials are defined as those porous materials with pore diameters less than 100 nm. Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of nanoporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nanostructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell technology, nanocatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials.

This book provides a series of systematic reviews of the recent developments in nanoporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc.

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Excitonic And Vibrational Dynamics In Nanotechnology: Quantum Dots Vs. Nanotubes

April 9, 2010 by · Leave a Comment 

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Rapid advances in chemical synthesis and fabrication techniques have led to novel nano-sized materials that exhibit original and often unforeseen properties. One of the greatest advantages of these nano-systems is that their electronic and optical properties can be controlled, not only by the material’s inherent features, but also by the sample’s size, shape, and topology. This flexibility makes them ideal for applications in several fields, ranging from electronics and optoelectronics to biology and medicine. However, in order to design nanoelectronic devices, a clear understanding of their fundamental properties is needed. Semiconductor quantum dots (QDs) and single-walled carbon nanotubes (SWCNTs) are two of the most promising examples of low-dimensional nanomaterials. These two types of nano-systems have been chosen for the extensive studies presented in this book.

The book investigates QDs and SWCNTs using quantum-chemical calculations that describe intricate details of excited state phenomena, and provides information about the mechanisms that occur on the atomic level and that are extremely difficult if not impossible to probe experimentally. It delivers, consistently and coherently, a novel approach to the nanomaterials which is promising for today’s technologies as well as their future. This approach elegantly overcomes computational difficulties known in the field, and shares ways to reach top performance in description of combined quantum effects of molecular vibrations and exciton formation on the realistic size numerical models. The reader will acquire the pioneering methodology supported by most recent original results, prospectively applicable to the design of new nano-devices.

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